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Toyota Embraces Hydrogen

Toyota is the world’s most successful car company. The Prius is the most popular gas-electric hybrid ever, with 3 million sold in 80 countries worldwide. Toyota can be said to have pioneered the first vehicle that has challenged the traditional internal combustion engine.
So why is the Japanese giant now moving away from hybrids and placing its bets on the hydrogen fuel cell?
It’s a tough question. Not many analysts can see the sense of it. Elon Musk dismisses the whole idea as “fool cells” and says it can’t succeed. Yet, Toyota maintains that there are inherent advantages in the technology that will eventually emerge. Most of all, the decision by Toyota, Honda and Hyundai to go with hydrogen instead of electric vehicles has set off a fierce debate on which technology — if either — represents the better route to replacing the internal combustion engine.
It is not as if this is a snap decision for Toyota. In 1992, the company set up two task forces — one to investigate the gas-electric hybrid and one to pursue the hydrogen vehicle. In 1997 the Japanese giant introduced the Prius, which has gone on to become one of the most successful models of all time. But work never stopped on the fuel cell project. Now, as company officials reportedly believe hybrid technology may have reached the point of diminishing returns, they feel it is time to move on to something new. “Of all the advanced power train systems we have in our portfolio,” Toyota Senior Vice President Bob Carter told Green Car Reports, “we see hydrogen fuel cells as being the no-compromise, primary-option vehicle for the next 100 years.”
All this is happening, of course, at the moment when Tesla seems to be proving that electric vehicles can go head-to-head with gas-powered cars. So the question is, what does Toyota see in hydrogen that can’t be achieved by following up with electrics?
Range is one answer. Toyota is still convinced that electric vehicles will never get beyond the 150-200-mile range that most EVs now achieve — although Tesla is already pushing toward 300. The new Toyota Fuel Cell Vehicle (FCV) that will go on sale in California next summer will have a range of 300 miles, with hopes of future improvement.
Even more important than range is refueling time. A fuel-cell vehicle can fill up at a hydrogen pump in ten minutes — still significantly longer than gasoline — but an EV takes from four to six hours. Even the new “superchargers” that Musk is installing around the country take 20 minutes to give a half-charge. But Musk is also working on a battery-pack replacement that would be faster than a gasoline fill-up.
Of course all this is predicated on having “filling stations” available, and on that score, hydrogen is even further behind. There are only 60 such facilities in the entire country. Tesla just announced its 100th supercharging station in April and that’s just a small part of the action. Most EV owners recharge at home and the electric grid is everywhere. Providing hydrogen around the country would require a whole new infrastructure.
Joseph Romm, who once promoted hydrogen cars as Assistant Secretary of Energy under Bill Clinton and later wrote the book, “The Hype About Hydrogen,” remains one of the fiercest critics of the technology. “Hydrogen is the smallest molecule and escapes almost any container,” he wrote in his blog, ThinkProgress. “It makes metals brittle. It is almost impossible to transport. These are physical barriers that will be very difficult to overcome.”
Another surprising aspect of hydrogen is that it is not particularly cheap. Unlike EVs, ethanol or methanol made from natural gas, hydrogen does not offer consumers any financial incentive. At the J.P. Morgan Auto Conference in New York last week, Senior Vice President Carter admitted that a full tank of hydrogen needed to carry the driver 300 miles will cost $50, slightly higher than ordinary gasoline. By contrast, the owner of a Prius only pays $21 for the same trip, and the owner of a Tesla Model S would pay $9.60 at off-peak rates. It’s hard to see how there is going to be any appeal to consumers.
Now it must be admitted that much of the fierce debate taking place on the Internet concerning fuel cells vs. EVs revolves around reducing carbon emissions rather than freeing ourselves from foreign oil. EV advocates imagine a grid running on wind and solar energy while H2 partisans envision windmills and solar collectors turning out prodigious amounts of hydrogen. Other environmental critics have argued that without a larger component of non-fossil-fuel sources generating the electricity, converting to electric vehicles will do nothing to reduce carbon emissions, although some people disagree with all this.
It sometimes seems as if we are trying to accomplish too many things at once. Putting more FCVs and EVs on the road would definitely move us toward energy independence. The source of the hydrogen or electricity can be sorted out later, and the same goes for methanol and ethanol as a liquid substitute for gasoline. These fuels might originally come from natural gas, but renewable sources such as landfill gas and manure piles could be substituted later.
The important thing is to keep moving forward on all fronts. No one knows when some vast new battery improvement or an entirely different method of extracting hydrogen may prove to be a game-changer. Toyota is doing this by pursuing the fuel cell vehicle — even though for the present the odds seem slightly stacked against it.

 
“Toyota FCV-R Concept WAS 2012 0629″ by Mariordo – Mario Roberto Durán Ortiz – Own work. Licensed under Creative Commons Attribution-Share Alike 3.0 via Wikimedia Commons.

Tesla Motors, Inc.’s Demand Is Growing Faster Than Production

Tesla’s (NASDAQ: TSLA ) Model S has been an enormous success. Not only has the all-electric luxury sedan been outselling all comparably priced cars in North America in 2013, but Tesla is expecting sales to increase by more than 50% this year. Most surprising of all, however, is that Tesla is achieving this without spending any money on advertising. How long can this trend continue?

 

What’s Behind Tesla’s Demand For $500 Million In Gigafactory Incentives

Tesla Motors has been playing a game of economic development poker for its $5 billion Gigafactory with five states — Arizona, California, Nevada, New Mexico and Texas. Last week, Tesla’s billionaire CEO Elon Musk revealed the bid he expects from the winning state. Musk, speaking on a conference call with analysts, said the place that gets the Gigafactory will need to put up 10 percent of the total cost, meaning $500 million.

How Can Tesla Motors Inc Create A Self-Driving Vehicle?

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CEO Elon Musk stated at the annual shareholder meeting last month that he was confident that Tesla would be able to roll out vehicles that could take the user from the highway entrance to the highway exit without touching any controls.

The journey of a thousand miles, replacement fuels and FFVs

The headlines recently have been terrible — a commercial plane was shot down over the Ukraine, there’s war in the Middle East and more. It makes you wonder, over and over again, about man and woman’s inhumanity to his or her fellow men and women.

While certainly not equal in impact on the world at the present time, I happened to run across one point of light concerning a set of innovations which, in the long run, could positively impact climate change, security and consumer choice issues. It was reflected in a couple of articles describing the partnership between the state of California’s Energy Commission and Cummins Engines to develop an E85-fueled engine that apparently cuts Co2 by up to 80 percent (read it in Fleets and Fuels) in medium-duty trucks.

According to Cummins Engines and the Commission, a relatively small 4-cylinder, 2.8-liter engine has been successfully subjected to 1,000 miles and 1,500 hours of testing. It is now going through validation tests in Sacramento.

The story is a welcome one. Cummins indicates that the engine can generate 250 horsepower and 450 pound-foot of torque using E85. “Using lignocellulosic-derived E85, the powertrain’s efficiency features 75 to 80 percent lower well-to-wheels carbon emissions than gas engines; depending on the drive cycle…Cellulosic E85 is not derived from tilling, fertilizing and harvesting corn…Using corn-derived E85, the high thermal efficiency and power-to-weight ratio of this engine results in 50 to 80 percent lower well-to-wheels carbon emissions compared with the gasoline engine.”

Based on the Cummins documentation, California’s Energy Commission indicates “that successful completion of the project may result in a new market for E85 fuel now dominated by gasoline and diesel in the 19,500 lb. step-van fleet market.” The agency estimates greenhouse-gas savings as great as 69 percent, or 10 to 20 percent using corn based ethanol.

Fortunately, the general principles guiding development of Cummins’ engine may help improve flex-fuel automobiles and grant Americans more confidence in the environmental, price and economic benefits associated with extended use of E85.

Lessons learned may increase the nation’s ability to reduce GHG emissions. Based on what Cummins has done, using smaller engines extends the benefit of E85. Diesel-like cylinder pressures are important. Ethanol’s high-octane rating generates more engine efficiency. Use of state-of-the art sensors for spark ignition and coordination of stop-and-start functions enhances efficiency and reduces emissions. E85 is clearly a safe fuel.

The knowledge gained from the Cummins effort could lead to better flex-fuel vehicles and could support the effort to use increased technology fixes for older, non-flex-fuel cars and FFV twins. Perhaps the biggest benefit from the partnership between California and Cummings relates to the boost it could give to the search for replacement fuels, as well as the myth-busting understanding it could provide consumers about the safety of E85. It is a safe fuel, assuming engine adaptation and software amendment.

Elon Musk’s proposal to share Tesla’s electric-car patents and ideas might at least encourage increased collaboration among FFV makers in Detroit and the potential players in the conversion industry that likely would emerge, subsequent to EPA testing and approval of older vehicles for conversion. Even improved cooperation at the margin would could expand production of new FFV vehicles and expand conversion of older vehicles. For automakers and makers of conversion kits, as well as developers of FFV software technology, successful collaboration would generate larger markets.

Increased use of E85 through conversion of existing cars and the increased production of new FFV vehicles would help meet national and local environmental objectives, reduce gasoline prices and provide consumers with lower fuel costs, apart from gasoline. Both would also reduce dependency on foreign oil. Paraphrasing the poet Robert Frost, while FFVs — new or converted — are on a road less traveled now, as John F. Kennedy indicated, the journey of a thousand miles must begin with one step. The road less traveled now has more replacement-fuel drivers and FFVs than ever. Because of this fact, the journey of a thousand miles toward alternative fuel choices has made progress and, hopefully soon, will move at a faster speed. Success will mean a better quality of life for us all. It’s good news!

Image credit: Wikimedia commons

Japan bets big on hydrogen fuel cells

Remember when Japan’s Ministry of Economy, Trade and Industry (METI) used to sit atop the Japanese industrial complex, steering it like some giant Godzilla hovering over the entire world?

Those were the days when Japan’s government-industry partnership was supposed to represent the future, when Michael Crichton wrote a novel about how Japan would soon devour America, when pundits and scholars were warning that we had better do the same if we hoped to survive – before, that is, the whole thing collapsed and Japan went into a 20-year funk from which it has never really recovered.

Well those days may be returning in one small part as METI prepares to direct at least half the Japanese auto industry into the production of hydrogen-powered fuel-cell cars.

“Japanese Government Bets the Farm on Fuel Cell Vehicles” ran one headline earlier this month and indeed there’s plenty at stake for everyone. The tip-off came at the end of May when Jim Lentz, CEO of Toyota’s North American operations, told Automotive News that electric vehicles are only “short-range vehicles that take you that extra mile…But for long-range travel, we feel there are better alternatives, such as hybrids and plug-in hybrids, and, tomorrow, fuel cells.” The target here, of course, is Tesla, where Elon Musk appears to be making the first inroads against gasoline-powered vehicles with his $35,000 Model E, aimed at the average car buyer. Toyota was originally in on that deal and was scheduled to supply the batteries until it pulled out this spring, ceding the job to Panasonic.

But all that was only a preview of what was to come. In early June, METI announced it would orchestrate a government-private initiative to help Toyota and Honda market fuel-cell vehicles in Japan and then across the globe. Of course that leaves out the other half of Japan’s auto industry, Nissan and Mitsubishi, pursuing their version of the EV, but maybe the Japanese are learning to hedge their bets.

The hydrogen initiative will put the fuel-cell vehicle front-and-center in the race to transition to other forms of propulsion and reduce the world’s dependence on OPEC oil. Actually, hydrogen cars have been in the offering for more than twenty years. In the 1990s soft-energy guru Amory Lovins put forth his Hypercar, a carbon-fiber vehicle powered by hydrogen fuel cells. In 2005, California Gov. Arnold Schwarzenegger inaugurated the “Hydrogen Highway,” a proposed network of hydrogen filling stations that was supposed to blanket the Golden State. Unfortunately, only ten have been built so far, and there are still no more than a handful of FCVs (hydrogen fuel cell vehicles) on the road. Mercedes, BMW, Audi and VW all have small lines but none are marketed very aggressively in the United States.

This time, however, there may be a serious breakthrough. After all, Toyota, Honda and METI are not just in the business of putting out press releases. Toyota will begin production of its first mass-market model in December and Honda will follow with a 5-passenger sedan next year. Prices will start in the stratosphere — close to $100,000 — but both companies are hoping to bring them down to $30,000 by the 2020s. Meanwhile, GM is making noises about a fuel-cell model in 2016 and South Korea’s Hyundai is already unloading its hydrogen-powered Tucson on the docks of California.

What will METI’s role be? The supervising government ministry promises to relax safety standards, allowing on-board storage of hydrogen at 825 atmospheres instead of the current 750. This will increase the car’s range by 20 percent and bring it into the 350-mile territory of the internal combustion engine. Like the ICE, hydrogen cars can “gas up” in minutes, giving them a huge leg up on EVs, which can take anywhere from 20 minutes with superchargers to eight hours with household plugs. METI has also promised to loosen import controls so that foreign manufacturers such as Mercedes-Benz can find their way into Japan. And, of course, it will seek reciprocal agreements so Toyota and Honda can market their models across the globe.

So will the one-two punch of government-and-industry-working-together be able to break the ice for hydrogen vehicles? California seems to be a particularly ripe market. Toyota is already the best-selling car in the state and the California Energy Commission is promising to expand the Hydrogen Highway to 70 stations by 2016. Still, there will be stiff competition from Elon Musk if and when his proposed Gigafactory starts turning out batteries by the millions. Partisans of EVs and fuel-cell vehicles are already taking sides.

In the end, however, the most likely winners will be consumers who will now have a legitimate choice between hydrogen vehicles and EVs. It may be a decade or more before either of these technologies makes a significant dent in our oil consumption, but in the end it will be foreign oil providers that will be feeling the pain.

Can supercapacitors replace batteries?

The electric car depends on batteries, and before EVs become a large chunk of our automotive fleet, there are probably going to be some changes.

Right now, Elon Musk is betting he can produce millions of small lithium-ion batteries not much bigger than the ones you put in your flashlight and string them together to power a $35,000 Tesla Model E over a range of 200 miles at speeds of up to 70-80 mph. The Model E also will also need an infrastructure of roadside “filling stations” and home chargers, although the best superchargers still take more than 20 minutes to achieve 80 percent capacity.

But there is another way to store electricity, long familiar to the designers of electrical circuits. It’s the capacitor, a device that stores a small current by static electricity rather than a chemical reaction. Capacitors sit in all of your electrical devices, from radio circuits to the most sophisticated laptops, and are essential to providing the steady electric current needed to run such electronics. But what if the concept of capacitors could be scaled up to the point where they could help power something as big as an electric vehicle? Granted, it’s a long, long way from the 1.5-volt capacitor in your iPad and powering a 4,500-pound Tesla along the Interstate, but researchers are out there probing and are already thinking in terms of a breakthrough.

Right now there’s a huge separation between the things that batteries can do and the things that capacitors can do. In a way they are complementary — the strengths of one are the weaknesses of the other. But researchers are working toward a convergence — or perhaps just a way of using them in tandem.

A battery employs chemistry by splitting ions in the electrolyte so that the negative ones gather on the cathode and the positive on the anode, building up a voltage potential. When they are connected externally an electric current flows. Batteries have a lot of energy density. They can store electricity up into the megawatt range and release a flow of electricity over long periods of time. The process can also be reversed, but, because the reaction is (once again) chemical, it can take a long time.

Capacitors store electrons as static electricity. A thundercloud is a great big capacitor with zillions of electrons clinging to the almost infinite surface area of individual raindrops. And as everyone knows, this huge stored capacity can be released in a “bolt of lightening.” Capacitors can be recharged almost instantly but also they release their energy almost instantly, rather than the even flow of a battery. One of their major uses is in flash photography. But their capacity for storing power is also limited. On a pound-for-pound basis, the best capacitors can only store one-fifth to one-tenth the equivalent of a chemical battery. On the other hand, batteries can start to wear out after five years, while supercapacitors last at least three times as long.

Back in the 1950s, engineers at General Electric, and later at Standard Oil, invented what have come to be called “supercapacitors.” Basically, a supercapacitor changes the surface material and adds another layer of insulating dielectric in order to increase storage capacity. Surface area is the key and engineers discovered that powdery, activated charcoal vastly increased the capacity of the storage plates. Dielectrics were also reduced to ultra-thin layers of carbon, paper or plastic, since the closer the plates can be brought together, the more intense the charge. Since then they have begun experimenting with graphene and other advanced materials that may be able to increase surface area by orders of magnitude. All of this means that much more electricity can be stored in a much smaller space.

But the problem of low energy density remains. Even supercapacitors can only operate at about 2.5 volts, which means they must be strung together in series in vast numbers in order to reach voltage levels required to power something like an electric car. This creates problems in maintaining voltage balance. Still, some supercapacitors are already being employed in gas-electric hybrids and electric buses in order to store the power siphoned off from braking.

Researchers in the field now see some possibility for convergence. Most exhilarating is the idea that the frame of the car itself could be transformed into a supercapacitor. Last month, researchers from Vanderbilt University published an online paper entitled, “A Multifunctional Load-Bearing Solid-State Supercapacitor,” in which they suggested that load-bearing materials such as the chassis of a car or even the walls of your house could be transformed into supercapacitors to store massive amounts of electricity on-site. Combined with advances in evening the flow of electrons from supercapacitors, this opens up whole new avenues of approach to the electric car.

All of these developments are a long way off, of course. Still, supercapacitors support the possibility of pulling out of your driveway in the morning and returning at night in your EV without needing to gas up with foreign oil at your nearest filling station.

From lab to market, it’s a long haul

The Energy Information Administration has done us an enormous favor by producing a simple chart to make sense of where the development of energy storage technology is going. Energy storage, as the EIA defines it, includes heat storage, and a quick look at the chart reveals that those forms that involve sheer physical mechanisms – pumped storage, compressed air and heat reservoirs – are much further along than chemical means of storage, particularly batteries.

The EIA divides the development of technologies into three phases – “research and development,” “demonstration and deployment” and “commercialization.” It also ranks them according to a factor that might be called “chances for success,” which is calculated by a multiple of capital requirements times “technological risk.”

As it turns out, only two technologies that could contribute to transportation are in the deployment stage while three more are in early development. The two frontrunners are sodium-sulfur and lithium-based batteries while the three in early stages are flow batteries, supercapacitors and hydrogen. The EIA refers to hydrogen as one of the ways of storing other forms of energy generation, particularly wind and solar. But hydrogen is also being deployed in hydrogen in hydrogen-fuel-cell vehicles that have already been commercialized.

Other than building huge pumped-storage reservoirs or storing compressed air in underground caverns, the chemistry of batteries is the most attractive means of storing electricity, which is the most useful form of energy. Batteries have always had three basic components, the anode, which stores the positive charge, the cathode, which stores the negative charge, and the electrolyte, which carries the charge between them. Alexander Volta designed the first “Voltaic pile” in 1800 by submerging zinc and silver in brine. Since then, battery improvements have involved finding better materials for all three components.

Lead-acid batteries have become the elements of choice in conventional batteries because the elements are cheap and plentiful. But lead is one of the heaviest common elements and becomes impractical when it comes to loading them aboard a vehicle.

The great advantage of lithium-ion batteries has been their light weight. The lithium substitutes for metal in both anode and cathode, mixing with carbon and iron phosphate to create the two charges. Li-ion, of course, is the basis of nearly all consumer electronics and has proved light and powerful enough to power golf carts. The question being posed by Elon Musk is whether they can be ramped up to power a Tesla Model S that can do zero-to-60 with a range of 300 miles.

Tesla is not planning any technological breakthrough, but will use brute force to try to scale up. Enlarging li-ion batteries tends to shorten their life so the Tesla will pack together thousands of small ones no bigger than a AA that will be linked by a management system that coordinates their charge and discharge. Musk is betting that economies of scale at his “Gigafactory” will lower costs so that the Model X can sell for $35,000. According to current plants, the Gigafactory will be producing more lithium-ion batteries than are now produced in the entire world.

In the sodium-sulfur battery, molten sodium serves as the anode while liquid sodium serves as the cathode. An aluminum membrane serves as the electrolyte. This creates a very high energy density and high discharge rate of about 90 percent. The problem is that the battery must be kept at a very high temperature, around 300 degrees Celsius, in order to liquefy its contents. A sodium-sulfur battery was tried in the Ford “Ecostar” demonstration vehicle as far back as 1991, but it proved too difficult to maintain the temperature.

Flow batteries represent a new approach where both the anode and cathode are liquids instead of solids. Recharging takes place by replacing the electrolyte. In this way, flow batteries are often compared to fuel cells, where a steady flow of hydrogen or methane is used to generate a current. The great advantage of flow batteries is that they can be recharged quickly by replacing the electrolyte, rather than taking up to 10 hours to recharge, as with, say, the Chevy Volt. So far flow batteries have relatively low energy density, however, and their use may be limited to stationary sources. A German-made vanadium-flow battery called CellCube was just installed by Con Edison as a grid-enhancement feature in New York City this month.

Supercapacitors use various materials to expand on the storage capacity devices in ordinary electric circuits. They have much shorter charge-and-discharge cycles but only achieve one-tenth of the energy density of conventional batteries. As a result, they cannot yet power vehicles on a stand-alone basis. However, supercapacitors are being used to capture braking energy in electric trams in Europe, in forklifts and hybrid automobiles. The Mazda6 has a supercapacitor that uses braking energy to reduce fuel consumption by 10 percent.

The concept of “storage” can be also be expanded to include hydrogen, since free hydrogen is not a naturally occurring element but can store energy from other sources such as wind and solar. That has always been the dream of renewable energy enthusiasts. The Japanese and Europeans are actually betting that hydrogen will prove to be a better alternative than the electric car. Despite the success of the Prius hybrid, Toyota, Honda and Hyundai (which is Korean) are putting more emphasis on their fuel cell models.

Finally, methanol can be regarded as an “energy storage” mechanism, since it too is not a naturally occurring resource but is a way to transmit the potential of our vast reserves of natural gas. Methanol proved itself as a gasoline substitute in an extensive experiment in California in the 1990s and currently powers a million cars in China. But it has not yet achieved the recognition of EVs and hydrogen – or even compressed natural gas – and still faces regulatory hurdles.

All these technologies offer the potential of severely reducing our dependence on foreign oil. All are making technical advances and all have promise. Let the competition begin.